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Asymmetric Halogeno-Bridged Complexes of the Late Transition Metals − A Computational and Experimental Study

✍ Scribed by Margarita Öhm; Axel Schulz; Kay Severin

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 277 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200012)2000:12<2623::aid-ejic2623>3.0.co;2-a

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✦ Synopsis

Metathesis reactions of dinuclear halo-bridged complexes of the late transition metals have been studied by NMR. For selected combinations of 15 different complexes, it has been shown that asymmetric complexes are formed in a dynamic equilibrium. The equilibrium constants have been calculated and the trends therein are discussed. A theoretical analysis of halo-bridged complexes containing (C 3 H 5 )MX, (H 3 P)MX 2 , [a]

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