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Computational simulation of Belousov–Zhabotinskii oscillating chemical reaction

✍ Scribed by Jie Ren; Jinzhang Gao; Wu Yang

Publisher
Springer-Verlag
Year
2008
Tongue
English
Weight
356 KB
Volume
12
Category
Article
ISSN
1432-9360

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Chemiluminescence (CL) occurs during reactions of several of the components of the CH2 (COOH)rKBr03-MnS04-H2S04 self-sustained system. In contrast to the kinetics determined using potentiometry and spectrophotometry, the CL intensity kinetic curve during the oxidation of manganese (11) ions by acidi

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## Abstract A detailed chemical mechanism for the cerium catalyzed bromination and oxidation of malonic acid by bromate has been developed, and complete numerical solutions have been obtained for the temporal behavior of the concentrations of the intermediate species. The many points of similarity

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## Abstract A Monte Carlo algorithm, capable of simulating numerically the time and space dependence of chemical concentrations in a reacting system, is presented. This method is used to study the phenomenon of trigger waves in the Oregonator model of the Belousov–Zhabotinskii reaction, including t

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Contrary to "classical" Belousov-Zhabotinskii (BZ) oscillatory systems, consisting of malonic acid, Ce (IV) -Ce (III) or Mn (III) -Mn (II) redox catalyst and KBrOa in solutions of H2SO4, where in an interval of added iodide initial concentrations 10 -4 mol din-3< [I-]o< 10 -a tool dm -3 the oscillal