𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chemiluminescent reactions in the Belousov-Zhabotinskii oscillating system

✍ Scribed by Zhuravlev, A. I. ;Trainin, V. M.

Publisher
John Wiley and Sons
Year
1990
Weight
490 KB
Volume
5
Category
Article
ISSN
0884-3996

No coin nor oath required. For personal study only.

✦ Synopsis

Chemiluminescence (CL) occurs during reactions of several of the components of the CH2 (COOH)rKBr03-MnS04-H2S04 self-sustained system. In contrast to the kinetics determined using potentiometry and spectrophotometry, the CL intensity kinetic curve during the oxidation of manganese (11) ions by acidic bromate has an extremum. Experimental dependences of the maximum CL intensity value on the initial reagent concentrations have been determined and compared with the results of the numerical simulation based on the commonly accepted Noyes-Field-Thompson mechanism.

📜 SIMILAR VOLUMES

A completely inorganic oscillating syste
A completely inorganic oscillating system of the Belousov–Zhabotinskii type
✍ Ľubica Adamčíková; Peter Ševčíak 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB

## Abstract An inorganic compound, NaH~2~PO~2~, has been found to generate temporal chemical oscillations in Belousov–Zhabotinskii type reactions when it is substituted for the organic reducing material. Gaseous products were removed by a constant flow of nitrogen carrier gas. Periodic Br~2~ evolut

Several types of oscillations in Belouso
Several types of oscillations in Belousov–Zhabotinskii reactions with amino acids as organic substrates
✍ Hexing Li; Yeping Xu; Minghui Wang 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract Under batch‐reactor conditions, 7 amino acids were employed as organic substrates in Belousov–Zhabotinskii (BZ) oscillations. These amino acids displayed different types of oscillations. Aspartic acid exhibited the classical BZ oscillations owing to the formation of oxalacetic acid (an

A dual-frequency Belousov Zhabotinskii o
A dual-frequency Belousov Zhabotinskii oscillating reaction with ethyl acetoacetate as organic substrate
✍ Leo F. Salter; John G. Sheppard 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

## Abstract The experimental behavior of the cerium‐ and manganese‐catalyzed Belousov Zhabotinskii oscillating reaction with ethyl acetoacetate as organic substrate has been investigated. Under certain conditions the system displays two types of temporal oscillations. Damped highfrequency oscillati