Computational Insights on the Structure and Properties of C 24 , C 18 B 3 N 3 , C 12 B 6 N 6 and Their Endohedral Complexes with Alkaline and Earth Alkaline Metals
✍ Scribed by Ghiasi, Reza; Pasdar, Hoda; Ghaffarpour, Zahra
- Book ID
- 120385800
- Publisher
- Taylor and Francis Group
- Year
- 2013
- Tongue
- English
- Weight
- 527 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1536-383X
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## Abstract The potassium salt K(C~5~H~5~BMe) (8) can be obtained from 2‐(Me~3~Sn)C~5~H~5~BMe (7)/KO__t__Bu in toluene in essentially quantitative yield. Metalation of 1‐(dimethylamino)‐3‐methylene‐1,2,3,6‐tetrahydroborinine (9) with MN(SiMe~3~)~2~ (M = Na, K) in toluene afforded the unsolvated sal
## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th