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Syntheses and reactivity of acetylide-containing clusters of group 1B metals VII. Preparation and possible structures of the novel pentanuclear [Au3Ag2(C2Ph)6]−, [Ag5(C2Ph)6]−, and [Ag4Cu(C2Ph)6]− clusters. The reactivity of the polymer complexes [{AuAg(C2Ph)2}n] and [{AuCu(C2Ph)2}n]

✍ Scribed by Omar M. Abu-Salah; Abdel Razzak A. Al-Ohaly; Ziad F. Mutter


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
606 KB
Volume
389
Category
Article
ISSN
0022-328X

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## Abstract Ph~3~SnN(SiMe~3~)~2~ (1) was prepared in good yields by reaction of [{NaN(SiMe~3~)~2~}~2~·THF] (2) with Ph~3~SnF. Treatment of 1 with [H(OEt~2~)~2~][H~2~N{B(C~6~F~5~)~3~}~2~] (4) in dichloromethane afforded the stannylium cation [Ph~3~Sn(OEt~2~)][H~2~N{B(C~6~F~5~)~3~}~2~] (5), which was