๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Computational comparison of Rh2(esp)2 and Rh2(O2CH)4 as catalysts in a carbenoid reaction

โœ Scribed by Hanne Therese Bonge; Tore Hansen

Book ID
104098175
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
492 KB
Volume
51
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

A computational study of Rh 2 (esp) 2 -catalysed cyclopropanation of styrene with ethyl bromodiazoacetate is presented. The calculated structures and the energy profile of the reaction show a high level of similarity between Rh 2 (esp) 2 , a catalyst with sizeable, tethered ligands, and the simplified model catalyst Rh 2 (O 2 CH) 4 .

๐Ÿ“œ SIMILAR VOLUMES

Comparative XPS study of Rh/Al2O3 and Rh
Comparative XPS study of Rh/Al2O3 and Rh/TiO2 as catalysts for NaBH4 hydrolysis
โœ Y.V. Larichev; O.V. Netskina; O.V. Komova; V.I. Simagina ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 629 KB

The catalysts Rh/Al 2 O 3 and Rh/TiO 2 for hydrogen production from NaBH 4 were prepared by deposition technique from RhCl 3 reduced by NaBH 4 and were studied by XPS and TEM. It was found that the RhCl 3 /Al 2 O 3 system is more stable comparing to RhCl 3 /TiO 2 which starts to decompose by weak he