β Scribed by Y.V. Larichev; O.V. Netskina; O.V. Komova; V.I. Simagina
No coin nor oath required. For personal study only.
The catalysts Rh/Al 2 O 3 and Rh/TiO 2 for hydrogen production from NaBH 4 were prepared by deposition technique from RhCl 3 reduced by NaBH 4 and were studied by XPS and TEM. It was found that the RhCl 3 /Al 2 O 3 system is more stable comparing to RhCl 3 /TiO 2 which starts to decompose by weak heat treatment. It was shown that NaBH 4 reduced RhCl 3 /TiO 2 (Al 2 O 3 ) to supported metal Rh nanoparticles in both cases. In the case of Rh/TiO 2 SMSI effect it was found after RT reduction. The SMSI (Strong Metal-Support Interaction) effect gave an explanation for the difference of activity between Rh/TiO 2 and Rh/Al 2 O 3 catalysts in hydrolysis reaction of NaBH 4 .
π SIMILAR VOLUMES
Characterization of TiO2-, ZrO2-and Al2O3-Supported Iron Catalysts as Used for CO2 Hydrogenation. -The catalytic performance in the synthesis of hydrocarbons others than methane from CO2 and H2 of the title catalysts, prepared by direct reduction in H2 atmosphere at 773 K of precursors obtained by i