✦ LIBER ✦

Computation of the direct adiabatic channel for the relaxation of electronically excited C2 H5 radical to give H + C2 H4

✍ Scribed by E.M. Evleth; H.Z. Cao; E. Kassab; A. Sevin

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 499 KB
Volume: 109
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85398-1

No coin nor oath required. For personal study only.

✦ Synopsis

Ab initio 3-31C + 3s RHF computations of the lowest escited state of the ethyl radical show that rhis species should be either directly dissociztive or predissochtive. There esists a direct excited-state surface taking zhe exited state adiabatically to the ground state of ethylene f H.

📜 SIMILAR VOLUMES

Kinetics of the reaction: 2C2H4 → C2H5 +

Kinetics of the reaction: 2C2H4 → C2H5 + C2H3· heat of formation of the vinyl radical

✍ G. Ayranci; M. H. Back 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 929 KB

The initial rates of formation of the major products in the thermal reactions of ethylene at temperatures in the neighborhood of 800 K have been measured in the presence and absence of the additives neopentane and ethane. It has been shown that in the absence of the additive the main initiation proc

Calculations of the Rate Constants for t

Calculations of the Rate Constants for the Hydrogen Abstraction Reactions C2H3+CH4→C2H4+CH3 and C2H3+C2H6→C2H4+C2H5

✍ Gui-xia Liu; Ze-sheng Li; Jing-fa Xiao; Jing-yao Liu; Qiang Fu; Xu-ri Huang; Chi 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB 👁 2 views

The electronic structures of [(C5H4XC6H5

The electronic structures of [(C5H4XC6H5)Cr(CO)3]− and (C6H5XC5H4)Mn(CO)3, (X = −, CO, CH2, C2H2)

✍ Noel J. Fitzpatrick; Niall J. Gogan; Pardeep K. Sayal 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 266 KB

A shock tube study of the reaction of th

A shock tube study of the reaction of the hydroxyl radical with H2, CH4, c-C5H10, and i-C4H10

✍ J. F. Bott; N. Cohen 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 725 KB

Reactions of the hydroxyl radical, OH, with several reactants have been studied near 1200 K in shock tube experiments in which UV absorption was used to monitor the OH concentration. The values of the rate coefficients were found to be 2.7 x lo", 2.6 X lo", 2.8 x and 1.26 x 1013 cm3/mol-s for the re

[(C5H5)Fe(C5H4CH2NMe2)] as a promoter fo

[(C5H5)Fe(C5H4CH2NMe2)] as a promoter for the synthesis of the 1,2-disubstituted ferrocenyl aldehydes [(C5H5)Fe(1,2-C5H3(CHO)(CH2NMe2)] and [(C5H5)Fe{1,2-C5H3(CHO)CH2NMe(CH2)2OCHCH2}]

✍ Béatrice Delavaux-Nicot; Yannick Guari; René Mathieu 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 242 KB

Structural chemistry of titanium and alu

Structural chemistry of titanium and aluminium bimetallic hydride complexes: VIII. Crystal and molecular structures of the complex (η5-C5H5)2Ti(η2-H)2Al(CH3)(μ2-H)2Ti(η5-C5H5)2, an effective catalyst for olefin hydrogenation, and its decomposition product, [(η5-C5H5)2Ti(η2-H)2Al(η2-H)-(η1:η5-C5H4) Ti(η5-C5H5)(μ2-H)]2 · C6H6

✍ A.I. Sisov; I.V. Molodnitskaya; B.M. Bulychev; E.V. Evdokimova; V.K. Bel'skii; G 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 601 KB