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Compounds with bridgehead nitrogen 53—13C NMR spectra and stereochemistry of perhydronaphthaleno[2,1-e]pyrido[1,2-c][1,3]oxazines

✍ Scribed by Trevor A. Crabb; Olive G. Roch; Brian Wood

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
337 KB
Volume
25
Category
Article
ISSN
0749-1581

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✦ Synopsis

The configurations and preferred conformations of some diastereoisomeric perhydronaphthaleno[2,1-elpyrido[ 1,2c][ 1,310xazines have been assigned by "C NMR spectroscopy. These results require reversal of two previous tentative configurational assignments based on 'H NMR spectroscopy, and also indicate the presence of non-chair conformations for cis-anti-cis-syn-cis-and trans-syn-cis-syn-ci-perhydronaphthaleno[2,l-e]pyrido[ 1,2-c][ 1,3]oxazine.

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