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Compounds with bridgehead nitrogen. 48—stereochemistry of the 5-methylperhydropyrido[3,2,1-i,j][3,1]-benzoxazines

✍ Scribed by Trevor A. Crabb; Philip A. Jupp; Christopher H. Turner

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
390 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Six of the eight possible diastereoisomeric 5‐methylperhydropyrido[3,2,1‐i,j][3,1]benzoxazines have been synthesized, and the utility of the C‐3 methylene proton NMR parameters [J(3ax3eq) and Δ3ax3eq] in the assignment of configurations has been demonstrated.

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