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Composition of impurities in tetrabutyltin prepared by grignard reaction

โœ Scribed by V. A. Umilin; Yu. N. Tsinovoi


Book ID
112481474
Publisher
Springer
Year
1968
Tongue
English
Weight
167 KB
Volume
17
Category
Article
ISSN
1573-9171

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The role of impurities in the reactions
โœ Richard B. Allen; Ronald G. Lawler; Harold R. Ward ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

It has been established by chemical (2a) and CIDNP (3,4) techniques that some transition metal salts catalyze the reaction of Grignard reagents with alkyl halides by a mechanism involving free radicals. Such catalysis is probably responsible for the Wurtz coupling side reaction which lowers the yiel