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Complexes with short Sn-Co bonds; preparation, structures and bonding in Et4N[trans-(Cl3Sn)2Co(CO)3] and [Co&{;(pz)3BH&};2][trans-&{;[(CO)4Co]Cl2Sn&};2Co(CO)3]

โœ Scribed by Owen J. Curnow; Brian K. Nicholson; Milton J. Severinsen


Book ID
107811716
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
894 KB
Volume
388
Category
Article
ISSN
0022-328X

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KU X-ray photoelectron (ESCA) ,qrectra of the Co 2p levels have been obtained in fnrns-and ci%[Co(NHa)&a ] Cl isomers\_ It is observed that these compounds slowly decompose under X-ray irradiation. A procedure is employed to record real spectra for both the trans and cis isomers without any sighican