KU X-ray photoelectron (ESCA) ,qrectra of the Co 2p levels have been obtained in fnrns-and ci%[Co(NHa)&a ] Cl isomers\_ It is observed that these compounds slowly decompose under X-ray irradiation. A procedure is employed to record real spectra for both the trans and cis isomers without any sighican
β¦ LIBER β¦
Solvent-Dependent 59Co NMR-Study of [Co(en)3]Cl3 and cis,trans-[Co-(en)2(N3)2]NO3
β Scribed by K.K.W. Ho; W.Y. Choy; C. Yuxin; S.C.F. Auyeung
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 318 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1064-1858
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## Abstract A series of mixedβmetal carbonyl clusters containing Co and Ru atoms was investigated by ^59^Co NMR and, for the first time in cluster chemistry, by ^99^Ru NMR. These techniques were successfully used to follow the reactivity of these complexes towards nitrosylation by NO^+^. Whereas [N