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Complexes of vanadium(V) with 8-quinolinolate and its substituted derivatives

โœ Scribed by R.P. Henry; P.C.H. Mitchell; J.E. Prue


Book ID
117122856
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
326 KB
Volume
7
Category
Article
ISSN
0020-1693

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Identification of the oxidation product
โœ Hepler, Michelle A. (author);Riechel, Thomas L. (author) ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 293 KB

We have reported previously [l] on the chemical and electrochemical syntheses of a binuclear mixedvalence vanadium(IV,V) complex, [(V'"OQz)-O-(V"-0Q2)]-(Q-= 8-quinolinol anion). This complex undergoes a reversible one electron per dimer oxidation in acetonitrile. The oxidation product is stable and