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Complexes of some 2-substituted thiazoles

โœ Scribed by E.J. Duff; M.N. Hughes; K.J. Rutt

Book ID
117122795
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
278 KB
Volume
6
Category
Article
ISSN
0020-1693

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Synthesis and characterization of some rhodium(III) cyclometallated complexes of 2-substituted benzylideneamino thiazoles
โœ Fatma E. M. El-Baih; Feriyal M. Abu-Loha; Zeinab Gomaa; Ibrahim M. Al-Najjar ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 308 KB

Schiff's bases derived from 2-aminothiazole and substituted benzaldehydes were reacted with [RhCI(PPh3)3] or [Rh-(/~-CI)(COD)] 2 (COD = 1,5-cyclooctadiene) in the presence of four equivalents of PPh3 to give Rh m cyclometallated complexes of the type [RhHCI{ (X-benzylidene) thiazole}-(PPh3)2], in wh