The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,
β¦ LIBER β¦
Complexes of ruthenium (II) and rhodium (I) with N-and P-donor macromolecular ligands: preparation and catalytic isomerisation of olefins
β Scribed by Carlo Carlini; Giuseppe Braca; Francesco Ciardelli; Glauco Sbrana
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 780 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0304-5102
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