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Complexes of molybdenum-(II) and -(IV) and tungsten(II) with sterically hindered thiolate ligands. Synthesis, reactivity, and X-ray crystal structures of [PPH4][Mo(SC6H2Pri 3,-2,4,6)3(CO)2] and [Mo(NNPh)(SC6H2Pri 3-2,4,6)3(NCMe)]

โœ Scribed by Blower, Philip J.; Dilworth, Jonathan R.; Hutchinson, John; Nicholson, Terry; Zubieta, Jon A.


Book ID
120825954
Publisher
The Royal Society of Chemistry
Year
1985
Tongue
English
Weight
923 KB
Volume
12
Category
Article
ISSN
1472-7773

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Insertion of CS2 into CuS bonds (II). Pr
โœ Kaluo Tang; Dedong Wu; Xianglin Jin; Youqi Tang ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 363 KB ๐Ÿ‘ 1 views

4, 6) 1, (1) reacts with a small amount of CS2 to give red crystals [ c u 6 ( s ~s c ~2 P r ' 3 - 2,4,6)2] .2CHCl3 . 4CH30H (2), and CS2 is inserted into two-thirds of the Cu-S bonds of complex (1). The unusual structure of complex (2) consists of six copper atoms linked through arenethiolate (RS-