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Complexes of ligands containing S O: I. Diphenylsulfoxide as ligand (Preliminary communication)

✍ Scribed by P. W. N. M. van Leeuwen; W. L. Groeneveld

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 184 KB
Volume: 85
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19660851114

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## Abstract The rhodium(I) complexes __trans__‐[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Scheme 4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Scheme 1__). The __trans__ coordination imposed by the rigid C‐spacer fr