𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Complexes of lanthanide nitrates with 2-n-acetylaminopyrimidine

✍ Scribed by N. Rajasekar; S. Soundararajan

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
377 KB
Volume
88
Category
Article
ISSN
0037-9646

No coin nor oath required. For personal study only.

✦ Synopsis

New complexes o f lanthanide n i t r a t e s with 2-N-acetylaminopyriuiidine (ApymH) of the composition Ln(ApymH) (110 ) where I n = La-Yb and Y have been synthesised and c h a r a c t e r i s c d by conductance, i n f r a r e d , 13C and ' H NEIR ( f o r La3+ and Y'?+ complexes only) and e l e c t r o n i c s p e c t r a . The molar conductance and i n f r a r e d s p e c t r a l d a t a s b w that all n i t r a t e groups are coordinated t o the metals. I R and IUR 2vidence point t o the b i d e n t a t e c h e l a t i o n of t h e l i g a n d t h m u e h the pyrimidine n i t r o g e n and oxygen o f the acetylamino group.

ble coordination number of ten has been assigned for a l l t h e complexes.

📜 SIMILAR VOLUMES

Complexes of diethyl-2-amino-2-oxoethylp
Complexes of diethyl-2-amino-2-oxoethylphosphonate with lanthanide nitrates
✍ Jordanka Petrova; Snezana Momchilova; Nikolay G. Vassilev; Erhard T. K. Haupt 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 83 KB 👁 1 views

## Abstract Lanthanide complexes LnL~2~(NO~3~)~3~ **3a–f** are obtained where Ln is La, Ce, Sm, Eu, Er, and Yb and L is the diethyl 2‐amino‐2‐oxoethylphosphonate. They were characterized by elemental analysis, IR, and NMR spectroscopy. Monodentate coordination by the phosphoryl group is suggested f

Studies On Rare-Earth Complexes with Cro
Studies On Rare-Earth Complexes with Crown Ethers. Part XXV. Synthesis, characterization, and structure of the complexes of lanthanide nitrates with 13-crown-4
✍ Tongbu Lu; Xin Wang; Minyu Tan; Yu Liu; Yoshihisa Inoue; Tadao Hakushi 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 370 KB 👁 1 views

The lanthanide nitrate complexes with 13-crown-4(13-C-4) have been prepared in AcOEt. These new complexes with the general formula Ln(N03),.(13-C-4) (Ln = La-Nd, Sm-Lu) have been characterized by means of elemental analysis, IR and 'H-NMR spectra, conductivity measurements, and TG-DTA techniques. Th

Synthesis, Characterization, and Crystal
Synthesis, Characterization, and Crystal Structure of Complexes of Lanthanide Picrates with N,N,N′,N′-tetraphenyl-3,6-dioxaoctanediamide
✍ Shixia Liu; Weisheng Liu; Minyu Tan; Kaibei Yu; Ganzu Tan 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 German ⚖ 365 KB

## Abstract Lanthanide picrate complexes with the ligand __N,N,N′,N__′‐tetraphenyl‐3,6‐dioxaactanediamide (tdd): [Ln(Pic)~3~(tdd)] (Ln = La, Nd, Eu, Tb, Er) have been prepared in a nonaqueous medium and characterized by elemental analysis, conductivity measurements, IR, and ^1^H‐NMR spectra. The cr

Syntheses, Crystal Structures and Proper
Syntheses, Crystal Structures and Properties of Lanthanide(III) Complexes with N-Protected Aminoacid of N-p-Tosylglycinate
✍ Man-Bo Zhang; Zi-Lu Chen; Rui-Xiang Hu; Fu-Pei Liang; Zhong-Yuan Zhou 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 125 KB 👁 2 views

Complexes {[Ln(H 2 O) 2 (TsGlyH) 3 ] m •nH 2 O} ∞ (Ln＝La (1), m＝2, n＝6; Nd (2), m＝2, n＝7; Eu (3), m＝2, n＝ 0; Gd (4), m＝2, n＝2; Er (5), m＝3, n＝5 and Yb (6), m＝3, n＝0, TsGlyH＝N-p-tosylglycine monoanion), have been prepared and characterized by IR spectra, elemental analysis, and TG-DTG. 4 and 5 were s