Complexes of disilicon hexachloride with trimethylamine
โ Scribed by A. Kaczmarczyk; G. Urry
- Book ID
- 118905458
- Publisher
- Elsevier Science
- Year
- 1964
- Weight
- 372 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0022-1902
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๐ SIMILAR VOLUMES
The zirconium(W) derivatives ZrX4\*2NMe3 (X = Cl, Br and I) have been obtained from direct reaction of the appropriate metal halide with an excess of trimethylamine. Structural evidence for a monomeric formulation is provided specifically for the chloride and bromide complexes. Spectral evidence for
l'Ee white monoadducts AsBr3\*NMe3, SbX3\* NMes (X = Cl, Br) and the pale yellow bisadducts SbX3\*2NMe3 (X = Cl, Br) have been prepared. Char-acter&&n follows from analytical and IR and NMR ('H and t3C) spectml data. Possible structures and their stereochemical implications are considered.