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Complexes of aromatic hydroxy compounds with ammonium salts and amines novel hydrogen-bonding networks.

โœ Scribed by A.W Hanson; A.W McClulloch; A.G McInnes


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
204 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Aromatic hydroxy compounds react with alkyl ammonium hydroxides or amines in aqueous solution to give n:l complexes, the aromatic portions of which are linked by multiple hydrogen bonds.

Quaternary ammonium phenoxides have been implicated as intermediates in a number of reactions including alkylation of phenols under phase transfer conditions (1, 2). Stable


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Proton-transfer photoreactions in hydrog
โœ H. Lemmetyinen; A.B. Demyashkevich; M.G. Kuzmin ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 343 KB

TIus study IS concerned wrth proton-trvnsfer photoreactrons III hydrogen-bonded complexes and the formatlon of Ionized forms of naphthols in the ground state, m the presence of crown ethers. It has been found that a loss m electroruc excltatton energy may occur during the proton transfer m the hydro