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Proton-transfer photoreactions in hydrogen-bonded complexes and the formation of ion pairs by aromatic hydroxy compounds in the presence of crown ethers

✍ Scribed by H. Lemmetyinen; A.B. Demyashkevich; M.G. Kuzmin

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 343 KB
Volume: 73
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)85211-0

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✦ Synopsis

TIus study IS concerned wrth proton-trvnsfer photoreactrons III hydrogen-bonded complexes and the formatlon of Ionized forms of naphthols in the ground state, m the presence of crown ethers. It has been found that a loss m electroruc excltatton energy may occur during the proton transfer m the hydrogen bond. The efficlencles of the observed radratronless deactwatlon processes are controlled by the nature of the exated proton donor.

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