Complexes of a porphyrin-like N4-donor Schiff-base macrocycle
✍ Scribed by Wilson (née Sanyal), Rajni K.; Brooker, Sally
- Book ID
- 119969115
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 1006 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1477-9226
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Silver(I)-templated cyclocondensation of pyridine-2,6\_dicarbaldehyde and 3-oxa-1,5-diammopentane yields a dinuclear silver(I) complex of the '2+2' tetraimine Schiff base macrocycle L,. The crystal structure of the complex recrystallised from acetonitrile shows the product of recrystallisation to be
The antiaromatic macrocycle 2 has been prepared by the reaction of the bipyrrole dialdehyde 1 with hydrazine. In the crystal structure of 2•DMSO molecule 2 is nearly planar, the mean deviation of the 28 atoms of the core from the best least-squares plane being 0.227 Å. AM1 geometric optimization of