Complexation of thiomalic acid with mercury(II) and lead(II) under physiological conditions
✍ Scribed by Masunobu Maeda; Kohji Okada; Kazuhiro Wakabayashi; Kohji Honda; Kaname Ito; Yoshiaki Kinjo
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 505 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0162-0134
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## Abstract magnified image A 1 : 2 copper–tripeptide complex, [Cu^II^(Boc‐His‐Gly‐His‐OMe)~2~]^2+^, was synthesized and structurally characterized. The absorption band at 577 nm suggests a square‐planar geometry around Cu^II^. The DNA‐binding and DNA‐cleavage properties of the Cu^II^ complex were
The effects of tetrakis(1-methylpyridinium-4-yl)porphyrinatomercury(II) [ Hg ( TMPyP )]^4+^(6) along with [ Pb ( TMPyP )]^4+^(7), [ Cd ( TMPyP )]^4+^(8), and [ H~2~( TMPyP )]^4+^(1) (free base porphyrin) on DNA cleavage by Haemophilus aegyptius (HaeIII) have been studied using gel electrophoresis, U