Complexation between tungsten(VI) and citrate: The crystal and molecular structure of a dinuclear complex, Na6[W2O5(cit)2]·10H2O
✍ Scribed by Johannes J. Cruywagen; Louis J. Saayman; Margaret L. Niven
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 300 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1572-8854
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The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,