Complex radical copolymerization of di-n-butylstannyl dimethacrylate with maleic anhydride
✍ Scribed by Z. M. O. Rzaev; S. G. Mamedova; G. A. Jusifov; F. B. Rustamov
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 331 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0887-624X
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Radical copolymerization of allyl acrylate (AA) and allyl methacrylate (AMA) as bifunctional monomers of donor (allyl) -acceptor (acryl) type with maleic anhydride (MA) as an acceptor monomer were carried out in metrhyl ethyl ketone (MEK) at 50-70ЊC in the presence of 2,2-azoisobutyronitrile (AIBN)
Under the influence of azobisisobutyronitrile, benzoselenophene and maleic anhydride slowly polymerize to form an alternating copolymer. The two comonomers form a charge-transfer complex (K AD at 30 ~ in chloroform: 022 1 mol-t). These properties of benzoselenophene are similar to those of benzothio
## Abstract Radical copolymerizations of allyl __a__‐(__N__‐maleimido)acetate (AMI) with styrene (__D__, electron‐donor) or maleic anhydride (__A__, electron‐acceptor) were carried out in benzene and/or methyl ethyl ketone (MEK) at 50–70°C in the presence of 2,2′‐azoisobutyronitrile (AIBN) as initi
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