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Charge-transfer complex formation and copolymerization of maleic anhydride with benzoselenophene

✍ Scribed by E.J. Goethals; G. Hubrecht; C. Verschuere

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 185 KB
Volume: 10
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(74)90139-6

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✦ Synopsis

Under the influence of azobisisobutyronitrile, benzoselenophene and maleic anhydride slowly polymerize to form an alternating copolymer. The two comonomers form a charge-transfer complex (K AD at 30 ~ in chloroform: 022 1 mol-t). These properties of benzoselenophene are similar to those of benzothiophene and indole but are different from those of benzofuran. It is possible that the charge-transfer complex plays a role in the copolymerization.

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