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Complex of CuIIwith a chiral Schiff base (H2L) derived from the natural monoterpene (+)-6h-pinene. Synthesis and the properties of the complex and its solvate with acetonitrile. Crystal structure of [Cu(HL)Cl]•H2O

✍ Scribed by T. E. Kokina; R. F. Klevtsova; L. A. Glinskaya; E. G. Boguslavskii; E. A. Koneva; K. P. Volcho; S. V. Larionov


Publisher
Springer
Year
2010
Tongue
English
Weight
414 KB
Volume
59
Category
Article
ISSN
1573-9171

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✍ Davi Fernando Back; Marco Aurélio Ballin; Gelson Manzoni de Oliveira 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 480 KB

The Schiff base ligand {3-hydroxyl-5-(hydroxymethyl)-2-methylpyridine-4-yl-methylene}benzohydrazide hydrochloride monohydrated {(hhmmbH)ClÁH 2 O} (1) was prepared by reaction of pyridoxine hydrochloride with benzoic acid hydrazide. The reaction of 1 with [VO(acac) 2 ] and triethylamine yields the ne