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A novel, more vivid Cu2Zn2SOD model: crystal structure and some properties of the Schiff base copper(II) complex: [Cu(appn)](ClO4)2·H2O

✍ Scribed by Cai-Ming Liu; Ren-Gen Xiong; Xiao-Zeng You; Hoong-Kun Fun; Kandasamy Sivakumar


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
314 KB
Volume
16
Category
Article
ISSN
0277-5387

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,