We report exact vibrational energies of all bound and numerous quasi-bound states of HCO for total angular momenta J=O and 1. TheJ= 0 and 1 calculations are done with a Legendre polynomial tit to the three-dimensional ab initio potential of Harding. Additional J= 0 calculations are done for a modifi
Complex L2 calculations of bound states and resonances of HCO and DCO
โ Scribed by Desheng Wang; Joel M. Bowman
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 573 KB
- Volume
- 235
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
We report new calculations of bound states and resonances of HCO and DCO for total angular momenta zero and 1, using a modified ab initio potential, which was previously adjusted to improve agreement with experiment for bound states of HCO. The method to calculate the resonances is based on a diagonalization of a complex Hamiltonian, which is given by the full-dimensional real Hamiltonian plus an optical potential. The new calculations focus on comparisons with new experiments on the bound states and resonances of DCO, as well as with previous and new experimental data on HCO bound states and resonances.
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