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Complex Formation of ICL670 and Related Ligands with FeIII and FeII

✍ Scribed by Stefan Steinhauser; Uwe Heinz; Mark Bartholomä; Thomas Weyhermüller; Hanspeter Nick; Kaspar Hegetschweiler

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
35 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Complex Formation of ICL670 and Related
Complex Formation of ICL670 and Related Ligands with FeIII and FeII
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## Abstract Complex formation of 4‐[3,5‐bis(2‐hydroxyphenyl)‐1,2,4‐triazol‐1‐__y__l]benzoic acid (ICL670, H~3~L^x^), 4‐[3,5‐bis(2‐hydroxyphenyl)‐1,2,4‐triazol‐1‐yl]benzosulfonic acid (H~3~L^y^), and 3,5‐bis(2‐hydroxyphenyl)‐1‐phenyl‐1,2,4‐triazole (H~2~L^z^) with Fe^3+^ and Fe^2+^ was investigated

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Synthesis, Structure and Characterizations in Solid State and Solution of Dinuclear Pentacoordinated FeII and MnII Complexes and of a Linear Tetranuclear FeIII Complex Obtained with the Ligand N,N,N′,N′-Tetrakis[(6-methyl-2-pyridyl)methyl]propane-1,3-diamine
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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr