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Aerobic FeIII–FeII Reduction in the Presence of 2,4,6-Tri(2-pyridyl)-1,3,5-triazine and Benzilic Acid: Synthesis and Characterization of a Heptacoordinate FeII–Nitrato Complex

✍ Scribed by Catherine P. Raptopoulou; Yiannis Sanakis; Athanassios K. Boudalis

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 353 KB
Volume: 2008
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200800560

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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr