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Complex formation by n-substituted acetoacetamides-IV Enthalpies and entropies of protonation and chelation of the acetoacetanilide anion

✍ Scribed by H.J. Harries; G. Wright

Book ID
118907285
Publisher
Elsevier Science
Year
1969
Weight
229 KB
Volume
31
Category
Article
ISSN
0022-1902

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Formation and Dissociation Mechanism of
Formation and Dissociation Mechanism of Amide Complexes, IV. Protonation and deprotonation of the Cu2+ and Ni2+ complexes of 3,7-diazanonanediamide and 3,7-diazanonane-N,N′-diethylamide
✍ Andreas D. Zuberbühler; Thomas A. Kaden 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 365 KB

## Abstract The protonation and deprotonation rates of the coordinated amide groups in the Ni^2+^ and Cu^2+^ complexes of 3,7‐diazanonanediamide (DANA) and in the Cu^2+^ complex of 3,7‐diazanonane‐N,N′‐diethylamide (DANEA) have been studied by stopped‐flow techniques. For the interconversion M(H~−2