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Complex Fluorides of Tetravalent Cobalt

✍ Scribed by Quail, J. W.; Rivett, G. A.

Book ID
118735469
Publisher
NRC Research Press
Year
1972
Tongue
French
Weight
222 KB
Volume
50
Category
Article
ISSN
0008-4042

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A metal-mediated addition of two carbenes across an alkyne is employed for the synthesis of (2-phenylsulfonyl)-1,3-dienes. Control of diene stereochemistry is achieved through an unprecedented fluoride-catalyzed isomerization of the cobalt diene intermediates.