Complex copper(II) fluorides: III. Crystal structure of Ba2CuV2F12: A new bidimensional MX4 network
✍ Scribed by J. Renaudin; Y. Laligant; M. Samouël; A. de Kozak; G. Ferey
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 396 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-4596
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1998 structure structure (solids and liquids) D 2000 ## 28 -004 Crystal Structure of a Complex Barium, Aluminum, Copper(II) Fluoride: Ba 4 Cu 2 Al 3 F 21 . -The title compound is prepared from BaF 2 , CuF 2 and AlF 3 . The orthorhombic crystal structure is solved in the space group P2 1 2 1 2 1 Z
Ba 5 Cu 2 Al 3 F 23 is monoclinic: a ؍ 28.44(2) A s , b ؍ 7.322(4) A s , c ؍ 27.95(2) A s , ؍ 108.95(3)3, Z ؍ 12. The crystal structure was solved in the space group P2 /c (no. 14), from X-ray single crystal data using 14,235 unique re6ections (5307 with F o / (F o ) > 4). It is built up f