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Complete assignments of the 1H and 13C NMR spectra of six highly functionalized neoclerodane diterpenoids

✍ Scribed by Benjamín Rodríguez

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
172 KB
Volume
39
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

An NMR study of six highly functionalized neoclerodane diterpenes belonging to both A/B cis and trans series is described. In addition to 1D NMR methods, 2D shift‐correlated experiments [^1^H,^1^H‐COSY, ^1^H,^1^H‐TOCSY, ^1^H,^13^C‐gHSQC‐^1^J(C,H), ^1^H,^13^C‐gHMBC‐^n^J(C,H) (n = 2 and 3)] and 2D ^1^H,^1^H‐NOESY were used for the complete and unambiguous ^1^H and ^13^C chemical shift assignments of these structurally complex diterpenoids. Copyright © 2001 John Wiley & Sons, Ltd.

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