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Complete assignment of the 1H and 13C NMR spectra of secoisolariciresinol diglucoside, a mammalian lignan precursor isolated from Linum usitatissimum

✍ Scribed by Stefano Chimichi; Massimo Bambagiotti-Alberti; Silvia A. Coran; Valerio Giannellini; Boris Biddau

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
62 KB
Volume
37
Category
Article
ISSN
0749-1581

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✦ Synopsis

A convenient isolation and purification protocol for secoisolariciresinol diglucoside (1), a precursor of the biologically active mammalian lignans enterolactone and enterodiol, from flax seed is reported together with an extensive 1D-and 2D-NMR study (GE-HSQC, GE-HMBC and NOESY) leading to its definitive characterization as 2,3-bis[(4-hydroxy-3-methoxyphenyl)methyl]-1,4-butanediyl bis-[R-(R Ł , R Ł )]-Λ‡-D-glucopyranoside.

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