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Complete 1H and 13C assignments of fluorinated analogs of dehydroepiandrosterone

✍ Scribed by Jason P. Burgess; James S. Wintermute; Brian F. Thomas; Izet M. Kapetanovic

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
91 KB
Volume
44
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The complete assignments of all ^1^H and ^13^C chemical shifts were made for the fluorinated dehydroepiandrosterone (DHEA) analog fluasterone, 2, and two potential in vivo metabolites 3 and 4. The assignments were made using a combination of one‐ and two‐dimensional NMR techniques (^1^H, ^13^C, gDQCOSY, gHSQC, gHMBC). Once the proton chemical shifts were assigned, the stereochemistry of the two hydroxylated analogs was determined using 2D ROESY experiments. Copyright © 2006 John Wiley & Sons, Ltd.

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