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Complementary local and extended views of bonding in the ThCr2Si2 and CaAl2Si2 structures

✍ Scribed by Chong Zheng; Roald Hoffmann

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
876 KB
Volume
72
Category
Article
ISSN
0022-4596

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Two new compounds were synthesized by heating mixtures of the elements at 975-1025 K and characterized by single-crystal X-ray methods. CaZn 2 Si 2 (a=4.173(2) ( A, c=10.576(5) ( A) and EuZn 2 Ge 2 (a=4.348(2) ( A, c=10.589(9) ( A) crystallize in the ThCr 2 Si 2 -type structure (space group I4/mmm;