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A Test of the Application of Extended Hückel Calculations to the ThCr2Si2 and CaAl2Si2 Structure Types: the Case of SrMn2P2 and BaMn2P2

✍ Scribed by Stephanie L. Brock; J.E. Greedan; Susan M. Kauzlarich

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
133 KB
Volume
109
Category
Article
ISSN
0022-4596

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Two new compounds were synthesized by heating mixtures of the elements at 975-1025 K and characterized by single-crystal X-ray methods. CaZn 2 Si 2 (a=4.173(2) ( A, c=10.576(5) ( A) and EuZn 2 Ge 2 (a=4.348(2) ( A, c=10.589(9) ( A) crystallize in the ThCr 2 Si 2 -type structure (space group I4/mmm;