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Competitive reactivity as a probe for reaction coordinates in gas-phase ion–molecule chemistry

✍ Scribed by Robert W. Holman; Terry L. Sumpter; John Farrar; Kurt Weigel; John E. Bartmess

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
113 KB
Volume
10
Category
Article
ISSN
0894-3230

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✦ Synopsis

Using the method of competitive reactivity of two functional groups in the same molecule, anionic elimination reactions show considerable kinetic selectivity for small differences in leaving group thermochemistry, in structures of the general type YCH 2 CH 2 CH 2 Z, where Y and Z are good anionic leaving groups.

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