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Competitive Formation of Helical Cycloocta- and Cyclododecapyrroles

✍ Scribed by Wytko, Jennifer A.; Michels, Martin; Zander, Lars; Lex, Johann; Schmickler, Hans; Vogel, Emanuel

Book ID
127161215
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
98 KB
Volume
65
Category
Article
ISSN
0022-3263

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Singlet oxygenation of cycloocta-1,3,5-t
Singlet oxygenation of cycloocta-1,3,5-triene: Formation of (4.2.2)- and (2.2.2)- cycloadducts.
✍ Waldemar Adam; Ihsan Erden πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 216 KB

Photosensitized singlet oxygenation of 1,3,5-cyclooctatriene affords the (4.2.2)-and (2.2.2)-type endoperoxides, which were reduced with diimide, thermally isomerized, and deoxygenated with triphenylphosphine. Cycloocta-1,3,5-triene (k) is a versatile substrate for cycloaddition in view of its dive