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Competitive electron capture in mixed clusters, X (HCN)m (X=C2H5OH, CO2, O2, and SF6)

✍ Scribed by Tatsuya Tsukuda; Makoto Nagaminé; Tahei Tahara; Takashi Nagata; Tamotsu Kondow

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 559 KB
Volume: 218
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)e1453-n

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✦ Synopsis

Anions of mixed clusters, X (HCN) ,,, (X = C2H50H, Cot, O2 and SF,), were produced by collisional electron transfer from high-Rydberg Kr atoms and were detected by mass spectrometry. For C2H50H(HCN),, the major product ions were cluster anions CN-(HCN),CIH50H, while in the case of X (HCN), with X = CO*, 02, and SFs, ions X-(HCN). were produced. The results demonstrate that the excess electron introduced in the mixed clusters is captured preferentially by the molecule which forms an anionic core with a larger energy release.

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