Competitive catalytic epoxidation and oxidative cleavage of stilbene by ruthenium complexes
โ Scribed by Antonino Morvillo; Mario Bressan
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 528 KB
- Volume
- 125
- Category
- Article
- ISSN
- 1381-1169
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๐ SIMILAR VOLUMES
A synthetic strategy was developed to anchor an amino acid L-valine on to styrene-divinylbenzene co-polymer beads with 8% and 6% cross linking. The polymeric ligands containing bidentate N,O donor sites were treated with a solution of ruthenium(III) chloride to form the metal complex on the support.
A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of -SiMe 3 group on the rate of epoxidation process.