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Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions

✍ Scribed by Abirami Srikanth; Gopalpur Nagendrappa; Srinivasan Chandrasekaran

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 137 KB
Volume: 59
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(03)01210-9

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✦ Synopsis

A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of -SiMe 3 group on the rate of epoxidation process.

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