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Competing concerted and radical mechanisms I: The 2-alkoxyquinoline-n-oxide rearrangement

โœ Scribed by F. Gerhart; L. Wilde


Book ID
104234578
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
165 KB
Volume
15
Category
Article
ISSN
0040-4039

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Evidence for radical mechanism and a cag
โœ John P. Lorand; Russell W. Grant; Mrs.Patricia A. Samuel ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 100 KB

We wish to report direct evidence for a homolytic scission-recombination mechanism in the thermal eMeisenheimer" rearrangement' of the title compound, I, to the hydroxylamine, II (equation I). This mechanism W&B apparently first proposed by Schgllkopf,3 who adduced threefold