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Competing [3+4]- and [2+4]-Cycloadditions of Allenyl Cations

✍ Scribed by Dr. Herbert Mayr; Inge K. Halberstadt


Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
305 KB
Volume
19
Category
Article
ISSN
0044-8249

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Chiral Cations in 4 + 3 Cycloadditions. -Chiral allylic acetal (I) reacts with furan in the presence of Lewis acids to give [4 + 3] cycloadducts with diastereoselectivities depending on the Lewis acid and the reaction conditions used. Similar cycloaddition between (I) and cyclopentadiene can be ach