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Comparisons of the reactions of chlorine and alkyl hypochlorites with aromatics in nitromethane

โœ Scribed by Heasley, Victor L.; Heasley, Gene E.; Ingle, D. Michael; Davis, Paul D.; Rold, Tracy L.

Book ID
126294467
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
620 KB
Volume
38
Category
Article
ISSN
0022-3263

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The reactions of hypochlorites with olef
The reactions of hypochlorites with olefins in nitromethane
โœ V.L. Heasley; G.E. Heasley; M.R. McConnell; K.A. Martin; D.M. Ingle; P.D. Davis ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 264 KB

In a recent attempt to add t-butyl hypochlorite to olefins such as styrene and l-hexene in nitromethane, we were surprised to find that the exclusive products of these rapid reactions are chloronitromethane (ClCHaNO =,I) and t-butyl alcohol in nearly quantitative yield. This reaction is outlined in