The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.
โฆ LIBER โฆ
Comparison of13CH3,13CH2D, and13CHD2methyl labeling strategies in proteins
โ Scribed by Jason E. Ollerenshaw; Vitali Tugarinov; Nikolai R. Skrynnikov; Lewis E. Kay
- Publisher
- Springer Netherlands
- Year
- 2005
- Tongue
- English
- Weight
- 878 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0925-2738
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## Dedicated to Professor Duilio Arigoni on the occasion of his 75th birthday We present calculations on the parity-conserving and the parity-violating potentials in several MeOH isotopomers for the torsional motion by the newly developed methods of electroweak quantum chemistry from our group. Th