Comparison of the reactivities of the radicals CF3, CH3, and CCl3
β Scribed by I. E. Chlenov; M. V. Bazilevskii
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1968
- Tongue
- English
- Weight
- 263 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine
The multiple-channel reactions OH 1 CH 3 SCH 3 ? products, CF 3 1 CH 3 SCH 3 ? products, and CH 3 1 CH 3 SCH 3 ? products are investigated by direct dynamics method. The optimized geometries, frequencies, and minimum energy path are all obtained at the MP2/6-311G(d,p) level, and energetic informatio
Ab initio UHF geometry investigation of the CBr3 radical and the SW Xa calculations for its ionization potential, eleo tron affinity and electronegativity are reported. A comparison is made with our previous results for the Cc13 and CF3 radicals.